Born in the village Marezige Palekh district, Ivanovo region. In 1951-1956 years Cicilia in Palekh art school. Teachers - A. V. Kotuhin, I. P. Vakurov, A. F. Kaurav. In 1956-1989, he worked at the Palekh art-production workshops.
Was engaged in monumental painting (painting the foyer of the cinema "Ruslan" in the town of Pushkin of the Leningrad region (1971-1972), Ivanovo Palace of culture of textile workers and technology to them. 30-letiya Pobedy (1974)). Themes of works: folklore, literature, genre scenes. Participant of exhibitions since 1978. The work of V. V. Mukhina stored in museums: the State Museum of Palekh art, the Ivanovo regional art Museum.